Zinc-Mediated Synthesis of Vinyl Selenide and GPx-like activity

Marcello Tiecco; Lorenzo Testaferri; Caterina Tidei; Gianni Pintus; Alessio Casagrande; Benedetta Battistelli; Claudio Santi

doi:10.3390/ecsoc-14-00454

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Zinc-Mediated Synthesis of Vinyl Selenide and GPx-like activity

Marcello Tiecco

Lorenzo Testaferri

Caterina Tidei

Gianni Pintus

Alessio Casagrande

Benedetta Battistelli

Claudio Santi

¹ Dipartimento di Chimica e Tecnologia del Farmaco Università di Perugia. Viadel Liceo 1 – Perugia – ITALY

Published: 30 October 2010 by MDPI in The 14th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-14-00454

Abstract: Phenyl selenol and the zinc-selenolate PhSeZnCl can be conveniently employed for the stereospecific and stereoselective synthesis of vinyl selenides. These reactions occur with moderate to high yields and can be accomplished in eco-compatible conditions using a biphasic acidic system or directly an aqueous suspension.

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