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Different influence of polyoxygenation on the catalytic activity of amido vs. amino isoborneols
Santiago de la Moya Cerero
*
,
*
,
T. de las Casas Engel
,
E. M. Márquez Sánchez-Carnerero
Published:
27 October 2010
by MDPI
in The 14th International Electronic Conference on Synthetic Organic Chemistry
session General Organic Synthesis
Abstract: A new series of polyoxygenated amido isoborneols has been synthesized and tested on the enantioselective addition of diethylzinc to benzaldehyde and the results compared to a series of related amino isoborneols. The observed different behavior has been explained on the basis of catalytic quelates previously proposed by us
T. de las Casas Engel
,
E. M. Márquez Sánchez-Carnerero
