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Different influence of polyoxygenation on the catalytic activity of amido vs. amino isoborneols
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1  Dpto. de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain.

Abstract: A new series of polyoxygenated amido isoborneols has been synthesized and tested on the enantioselective addition of diethylzinc to benzaldehyde and the results compared to a series of related amino isoborneols. The observed different behavior has been explained on the basis of catalytic quelates previously proposed by us