In this research, photocatalysts based on TiO2 modified by fluorination and platinum addition were evaluated in the glycerol oxidation. These materials were characterized by different instrumental analysis techniques to determine the physicochemical properties. It was found that the surface modification lead to improve the materials absorption in the Visible region of the electromagnetic spectra and to increase the surface area of TiO2. By HPLC analysis was possible to observed that the photocatalysts 0.5% Pt-F-TiO2 showed the highest yield and selectivity towards glyceraldehyde (GAL). It was also observed that the increase in the platinum content until values of 2% had a negative effect in the effectiveness of fluorinated Titania in the glycerol photo-oxidation. The fluorination and platinum addition modify some physicochemical properties of TiO2, leading also to modify the reaction mechanism and selectivity during glycerol partial photo-oxidation and the dose of photocatalysts is an important reaction condition to obtain GAL and Dyhidroxyacetone (DHA) with yields above to 70%.
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Fluorinated and platinized Titania for Glycerol oxidation
Published: 10 November 2020 by MDPI in 2nd International Online-Conference on Nanomaterials session Nanotechnology for Energy, Environment, Catalyst and Sensing
Keywords: Glycerol; oxidation; Pt-F-TiO2; Glyceraldehyde; Dihydroxyacetone