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Efficient Catalytic Oxidation of Cyclohexane by Metalloporphyrins Encapsulated Mesoporous MCM-48

Mansoor Anbia

Rahmatollah Rahimi

Nafiseh RahmaniKhalili

Published: 05 November 2010 by MDPI in The 14th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

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Anbia, M.; Rahimi, R.; RahmaniKhalili, N. Efficient Catalytic Oxidation of Cyclohexane by Metalloporphyrins Encapsulated Mesoporous MCM-48, in Proceedings of the 14th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2010, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-14-00496

Catalytic oxidation of cyclohexane by two metalloporphyrins {manganese and iron 5, 10, 15, 20-meso-tetrakis-(p-chlorophenyl) porhyrin}immobilized in mesoporous MCM-48 with TBHP in acetonitril was investigated. It was found that immobilization significantly enhances catalytic activity as compared to the homogenous system.

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