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SYNTHESIS OF DICOMPARTIMENTAL SCHIFF BASE LIGANDS. CRYSTAL STRUCTURE OF (N-N'-BIS(3- METHOXY or 3-ETHOXYSALICYLIDENE)-1,2-DIAMINE-2-METHYLPROPANE
M. J. Rodríguez-Doutón
,
M. Maneiro
,
A. M. González-Noya
,
B. Fernández
,
*
,
M. A. Vázquez- Fernández
Published:
25 October 2010
by MDPI
in The 14th International Electronic Conference on Synthetic Organic Chemistry
session General Organic Synthesis
Abstract: The condensation of 3-methoxy or 3-ethoxy-2-hydroxybenzaldehyde and 1,2 diamine -2-methylpropane, to yield at the dianionic hexadentate Schiff base ligands H2 Ln (H2 L1 , H2 L2 respectively). The ligands have been characterised by elemental analysis, IR, 1H and 13C NMR spectroscopies and mass spectrometry (ES). The crystal structure of the two ligands was solved by X-ray crystallography, revealing its ability to bind metal centres.
Keywords: Supramolecular Chemistry / Dicompartimental Schiff bases / Hydrogen bonds / Manganese
M. Rodríguez-Doutón
,
M. Maneiro
,
A. González-Noya
,
B. Fernández
,
M. Vázquez- Fernández
